Direct calculation of interfacial tensions from computer simulation: Results for freely jointed tangent hard sphere chains

We develop a methodology for the calculation of surface free energies based on the probability distribution of a wandering interface. Using a simple extension of the NpT sampling, we allow the interface area to randomly probe the available space and evaluate the surface free energy from histogram analysis and the corresponding average. The method is suitable for studying systems with either continuous or discontinuous potentials, as it does not require explicit evaluation of the virial. The proposed algorithm is compared with known results for the surface tension of Lennard--Jones and Square Well fluid, as well as for the interface tension of a bead--spring polymer model and good agreement is found. We also calculate interfacial tensions of freely jointed tangent hard sphere chains on athermal walls for a wide range of chain lengths and densities. The results are compared with three different theoretical approaches, Scaled Particle Theory, the Yu and Wu density functional theory and an analytical approximation based on the latter approach. Whereas SPT only yields qualitative results, the last two approaches are found to yield very good agreement with simulations.Comment: 20 pages, 6 figures, Phys. Rev. E in press

The healing mechanism in artificially created circumscribed defects in the femora of albino rats

KI

Preliminary Results on Chemical Thinning of Apple Blossoms with Ammonium Thiosulphate, NAA, and Ethephon

Preliminary tests were carried out using ammonium thiosulphate as a chemical thinning agent for apple ('Cox's Orange Pippin' and 'Braeburn') blossoms. Ethephon and NAA (1-napthylacetic acid) were included for comparison. Whole tree sprays of 37g/l ammonium thiosulphate over-thinned 'Cox's Orange Pippin' blossoms and severely scorched blossoms, foliage, and apical meristems. Ethephon at 0.35 g/l also over-thinned, and NAA thinned to an intermediate extent when compared with the controls. When the lower concentration of 3.7 g/l ammonium thiosulphate was directly applied to stamens and styles of 'Braeburn' blossoms by brush, initial fruit set was only 30% that of untreated blossoms. When 0.35 g/I ethephon was directly applied by brush to spur leaves or petals of 'Braeburn' blossoms at pink bud, initial fruit set was only 23% that of untreated blossoms. lt is concluded that ammonium thiosulphate has the potential to thin apple blossoms. Further experiments to define optimum concentrations and spray volumes are needed

Chalcophile Element Constraints on the Sulfur Content of the Martian Mantle

The sulfur content of the Martian mantle is critical to understanding volcanic volatiles supplied to the surface of Mars and possibly climate. In the absence of Martian mantle rocks, sulfur content of the mantle has been inferred from S contents of Martian meteorites or from sedimentary sulfate abundances. Estimates of the sulfur content of the Martian mantle vary from 390-2,000 ppm, all of which are higher than that of the terrestrial mantle (~250 ppm;). Residual sulfide in the Martian mantle controls the distribution of chalcophile elements during partial melting. In this study, we report new analyses of Martian meteorites, and use the incompatible behavior of As, Tl and Pb to infer the sulfide mode of the Martian mantle using a different set of assumptions than those of prior studies

Integer generalized inverses of incidence matrices

AbstractGraphical procedures are used to characterize the integral {1}- and {1, 2}-inverses of the incidence matrix A of a digraph, and to obtain a basis for the space of matrices X such that AXA = 0. These graphical procedures also produce the Smith canonical form of A and a full rank factorization of A using matrices with entries from {-1, 0, 1}. It is also shown how the results on incidence matrices of oriented graphs can be used to find generalized inverses of matrices of unoriented bipartite graphs

Tin Abundances Require that Chassignites Originated from Multiple Magmatic Bodies Distinct from Nakhlites

Meteorites from Mars lack field context but chemical and chronologic studies have revealed remarkable links between nakhlites and chassignites. A widely held consensus is that nakhlites and chassignites originated from a large, single differentiated flow or shallow intrusive [1-5]. An Ar-Ar study assumed multiple flows based on resolvable age differences between meteorites [6], but did not address the possibility of differential cooling in a large, shallowly emplaced intrusion [1]. REE abundances in pyroxenes from nakhlites and Chassigny led [7] to argue for derivation of these rocks from distinct magmas. Volatile abundances (F, Cl, OH) in chlorapatites indicated that the entire suite of nakhlites and chassignites experienced hydrothermal interaction with a single fluid supporting a single body origin [4]. The discovery of a new chassignite, NWA 8694, extended the Mg# range from 80-54, providing a closer link to nakhlites but revealed the petrological difficulty of fractionating a single body of liquid to yield a series of olivine cumulates with such a large Mg# range [8]. When mafic magmas are emplaced into the crust, crustal assimilation can impart distinct elemental signatures if the country rock has experienced sedimentary or hydrothermal processing [9]. In this work, we used Sn abundances of nakhlites and chassignites to show that these rocks were crystallized from distinct magma batches, providing vital contextual clues to their origin

A determination of the strange quark mass for unquenched clover fermions using the AWI

Using the O(a) Symanzik improved action an estimate is given for the strange quark mass for unquenched (nf=2) QCD. The determination is via the axial Ward identity (AWI) and includes a non-perturbative evaluation of the renormalisation constant. Numerical results have been obtained at several lattice spacings, enabling the continuum limit to be taken. Results indicate a value for the strange quark mass (in the MSbar-scheme at a scale of 2GeV) in the range 100 - 130MeV.Comment: 6 pages, contribution to Lattice2005(Hadron spectrum and quark masses), uses PoS.cl

Percutaneous coronary intervention in the elderly: changes in case-mix and periprocedural outcomes in 31758 patients treated between 2000 and 2007

<p>Background: The elderly account for an increasing proportion of the population and have a high prevalence of coronary heart disease. Percutaneous coronary intervention (PCI) is the most common method of revascularization in the elderly. We examined whether the risk of periprocedural complications after PCI was higher among elderly (age ≥75 years) patients and whether it has changed over time.</p> <p>Methods and Results: The Scottish Coronary Revascularization Register was used to undertake a retrospective cohort study on all 31 758 patients undergoing nonemergency PCI in Scotland between April 2000 and March 2007, inclusive. There was an increase in the number and percentage of PCIs undertaken in elderly patients, from 196 (8.7%) in 2000 to 752 (13.9%) in 2007. Compared with younger patients, the elderly were more likely to have multivessel disease, multiple comorbidity, and a history of myocardial infarction or coronary artery bypass grafting (χ2 tests, all P<0.001). The elderly had a higher risk of major adverse cardiovascular events within 30 days of PCI (4.5% versus 2.7%, χ2 test P<0.001). Over the 7 years, there was a significant increase in the proportion of elderly patients who had multiple comorbidity (χ2 test for trend, P<0.001). Despite this, the underlying risk of complications did not change significantly over time either among the elderly (χ2 test for trend, P=0.142) or overall (χ2 test for trend, P=0.083).</p> <p>Conclusions: Elderly patients have a higher risk of periprocedural complications and account for an increasing proportion of PCIs. Despite this, the risk of complications after PCI has not increased over time.</p&gt

Moir\'e patterns in quantum images

We observed moir\'e fringes in spatial quantum correlations between twin photons generated by parametric down-conversion. Spatially periodic structures were nonlocally superposed giving rise to beat frequencies typical of moir\'e patterns. This result brings interesting perspectives regarding metrological applications of such a quantum optical setup.Comment: 4 pages, 5 figure